THIS IS A FILE WITH THE GCMC ADSORPTION ISOTHERMS OF METHANE IN THE SLIT-SHAPED CARBON PORES
IT WAS PRODUCED BY V.YU. GUSEV, N. SEATON AND J.A. O'BRIEN AS DESCRIBED IN THE PAPER
GUSEV V., SEATON N., AND O'BRIEN J.
A SELF-CONSISTENT METHOD FOR CHARACTERIZATION OF ACTIVATED CARBONS USING SUPERCRITICAL ADSORPTION AND GRAND
CANONICAL MONTE-CARLO SIMULATIONS.
LANGMUIR, 13, 10, 2815-2821, 1997
THIS DATA IS GRANTED BY THE AUTHORS FOR COMMERCIAL AND NON-COMMERCIAL USE WITH NO WARANTY OF ANY KIND.
REFERENCING THE ABOVE PAPER IS REQUIRED
_______________________________________________________________________________________________
308.15 k - temperature of experiment and GCMC simulations
40 - number of pore widths
18 - number of pressure points
The line below is the list of pore widths determined between the centers of outer carbon atoms in units of methane Lennard Jones diameters (3.81 A)
1.65 1.66 1.67 1.68 1.69 1.7 1.8 1.9 2 2.1 2.2 2.3 2.4 2.5 2.6 2.7 2.8 2.9 3 3.1 3.2 3.3 3.4 3.5 4 5 6 7 7.5 8 8.5 9 9.5 10 10.5 11 12 13 14 15
The following is the 18x40 matrix of all isotherms. It is designated "A" in the above paper.
Adsorption density is given in mol/cc units
1.68412E-07 5.33218E-07 1.31095E-06 2.39464E-06 4.24653E-06 4.55097E-06 6.91821E-05 0.000204317 0.000173622 0.000109238 6.45368E-05 3.95521E-05 2.59494E-05 1.83391E-05 1.38176E-05 1.09588E-05 9.0545E-06 7.68362E-06 6.74943E-06 6.01369E-06 5.46301E-06 5.00038E-06 4.64881E-06 4.33339E-06 3.34877E-06 2.41252E-06 1.91282E-06 1.60693E-06 1.48707E-06 1.38148E-06 1.2904E-06 1.2502E-06 1.1434E-06 1.08167E-06 1.02565E-06 9.82229E-07 8.89498E-07 8.16748E-07 7.56761E-07 7.06981E-07
4.08466E-07 1.42179E-06 3.13174E-06 5.91928E-06 1.02392E-05 1.11397E-05 0.000170086 0.000496303 0.000421573 0.000266611 0.000157883 9.69663E-05 6.36012E-05 4.49404E-05 3.39078E-05 2.68483E-05 2.22263E-05 1.89945E-05 1.66068E-05 1.48133E-05 1.34122E-05 1.23219E-05 1.14184E-05 1.07123E-05 8.21833E-06 5.92676E-06 4.71452E-06 3.94843E-06 3.67634E-06 3.40765E-06 3.18447E-06 3.0288E-06 2.82716E-06 2.68117E-06 2.5381E-06 2.39557E-06 2.19518E-06 2.01742E-06 1.86551E-06 1.73805E-06
8.77498E-07 3.06316E-06 6.63807E-06 1.26783E-05 2.20902E-05 2.40623E-05 0.00036305 0.001042752 0.000888843 0.000565825 0.000337529 0.000207126 0.000137173 9.68532E-05 7.30292E-05 5.78758E-05 4.78777E-05 4.07088E-05 3.57355E-05 3.19671E-05 2.88532E-05 2.65288E-05 2.45157E-05 2.30243E-05 1.77582E-05 1.26939E-05 1.01418E-05 8.45897E-06 7.87718E-06 7.30695E-06 6.82611E-06 6.39254E-06 6.03679E-06 5.71549E-06 5.41489E-06 5.17727E-06 4.72089E-06 4.33837E-06 3.99876E-06 3.75543E-06
1.88709E-06 6.53917E-06 1.44672E-05 2.76318E-05 4.7998E-05 5.1788E-05 0.000767629 0.002145419 0.001852411 0.001193221 0.000716102 0.000443799 0.000294754 0.000208642 0.000157565 0.00012501 0.000103423 8.81359E-05 7.72568E-05 6.89024E-05 6.25273E-05 5.74676E-05 5.33184E-05 4.97092E-05 3.84371E-05 2.74675E-05 2.18467E-05 1.84496E-05 1.68661E-05 1.57719E-05 1.47221E-05 1.38572E-05 1.30313E-05 1.23076E-05 1.1742E-05 1.11974E-05 1.02017E-05 9.34672E-06 8.68639E-06 8.02373E-06
3.46499E-06 1.20795E-05 2.70039E-05 5.0852E-05 8.83441E-05 9.58672E-05 0.001364962 0.003652925 0.003161837 0.002120607 0.001292007 0.000813375 0.000540743 0.00038621 0.000291502 0.000232238 0.000192474 0.000163833 0.000143896 0.000128346 0.000116178 0.000106579 9.87511E-05 9.19814E-05 7.05902E-05 5.08668E-05 4.05896E-05 3.38419E-05 3.12114E-05 2.91601E-05 2.73331E-05 2.55536E-05 2.41904E-05 2.29836E-05 2.1715E-05 2.07397E-05 1.90162E-05 1.73817E-05 1.6038E-05 1.50999E-05
5.97798E-06 2.07602E-05 4.65676E-05 8.82267E-05 0.000152407 0.000165326 0.002220394 0.005493529 0.004808231 0.003353784 0.002140254 0.001367666 0.00092041 0.000657914 0.000501159 0.000399366 0.000332348 0.000284081 0.000248875 0.00022135 0.000200417 0.000183814 0.000170703 0.000158652 0.000122363 8.7935E-05 7.02341E-05 5.88622E-05 5.42492E-05 5.01683E-05 4.6946E-05 4.45275E-05 4.17562E-05 3.96792E-05 3.75391E-05 3.56552E-05 3.26664E-05 2.99417E-05 2.7691E-05 2.57111E-05
1.02978E-05 3.49364E-05 7.81549E-05 0.000148154 0.000256616 0.000277951 0.003391817 0.007521298 0.006669278 0.004934759 0.00331347 0.00219721 0.001508105 0.001093652 0.000838567 0.000674653 0.000560783 0.000482988 0.000423655 0.000377896 0.000341315 0.000312698 0.00028937 0.000268504 0.000206143 0.000147617 0.000118051 9.90033E-05 9.17945E-05 8.4647E-05 7.96204E-05 7.48314E-05 7.04014E-05 6.65514E-05 6.28779E-05 6.03011E-05 5.46273E-05 5.03892E-05 4.64867E-05 4.36267E-05
1.93526E-05 6.52851E-05 0.000145968 0.000277763 0.000476611 0.000519386 0.005060136 0.009958751 0.008956388 0.007117315 0.005200746 0.003693912 0.002659798 0.001983113 0.001551543 0.001262552 0.001064625 0.000923562 0.000813519 0.000721318 0.000652521 0.000593768 0.000547576 0.000512671 0.000390732 0.000278093 0.000223364 0.000185667 0.000172494 0.000160452 0.000150371 0.000141268 0.000132468 0.000125955 0.000119805 0.000113488 0.000103135 9.54691E-05 8.79222E-05 8.16633E-05
3.67594E-05 0.000127113 0.000283347 0.000531883 0.000910748 0.000978678 0.006951794 0.011993453 0.010963346 0.00924522 0.007348439 0.005703687 0.004423543 0.003472681 0.002826779 0.002372285 0.002040892 0.001791904 0.00158781 0.001411993 0.001268639 0.001159257 0.001064577 0.000984218 0.000750206 0.000532655 0.000424426 0.000354112 0.000329127 0.000305632 0.000283733 0.000269238 0.000252504 0.000240176 0.000226355 0.00021564 0.000196653 0.000181025 0.000168144 0.000155436
6.73929E-05 0.000232804 0.000514628 0.000963525 0.001639127 0.001719718 0.008354999 0.013489717 0.012421151 0.010788857 0.009195087 0.007588536 0.006302608 0.00535542 0.004622 0.004111699 0.003746598 0.003390791 0.003116053 0.002756525 0.002504796 0.002294956 0.002116296 0.001955549 0.001480772 0.001038901 0.000837249 0.000699927 0.00064852 0.000602072 0.000564734 0.000482993 0.000503015 0.000474189 0.00044876 0.000423672 0.000379315 0.000348659 0.000323202 0.000298377
0.000118397 0.000412068 0.000903856 0.001680017 0.002787276 0.002829225 0.00953495 0.014601848 0.013518789 0.011924272 0.010506598 0.009136846 0.008032882 0.00718166 0.006609671 0.006266586 0.006035213 0.005717828 0.005264131 0.004824872 0.004341338 0.003926982 0.003601522 0.003266309 0.002452251 0.00175046 0.001380429 0.001167082 0.001076288 0.000998291 0.000942215 0.000834525 0.000825519 0.000792117 0.000746985 0.000711367 0.000643221 0.000582568 0.000538238 0.000497401
0.000193206 0.000668767 0.001478414 0.002673158 0.004256906 0.004181183 0.010347603 0.01537866 0.014177098 0.012793953 0.011373902 0.010273513 0.009281544 0.008598004 0.008294026 0.008343124 0.008505401 0.008399792 0.007902902 0.007255286 0.006583233 0.005993099 0.00551471 0.005091264 0.003824613 0.002679281 0.002138184 0.001784852 0.001644024 0.001542676 0.001455487 0.001322627 0.00128152 0.001206996 0.001147551 0.001091842 0.000995703 0.000910019 0.000844596 0.000781829
0.000272833 0.000983384 0.002127423 0.003747844 0.00573637 0.005362926 0.010899019 0.015799362 0.014599259 0.013141623 0.011883081 0.010848018 0.01004289 0.009569191 0.009489348 0.009926389 0.010256415 0.010441691 0.009867787 0.009293676 0.008521335 0.007906843 0.007324019 0.006838334 0.005266837 0.003663023 0.00292216 0.002432332 0.002249908 0.002114248 0.001979303 0.001801297 0.001768092 0.001651597 0.001594909 0.001501465 0.001368426 0.001234032 0.001152978 0.001057329
0.000348295 0.00125909 0.002694896 0.004619314 0.006872199 0.006245304 0.011251277 0.016031763 0.014821684 0.013476487 0.012149739 0.011057849 0.010459923 0.010073954 0.010216288 0.010837045 0.011537573 0.011563895 0.011100245 0.010471079 0.009785916 0.009048865 0.008435449 0.007981951 0.006351893 0.004462282 0.00350116 0.00294937 0.002750988 0.002550161 0.002389881 0.00220656 0.002138732 0.002010518 0.001923914 0.00181006 0.001636343 0.001513444 0.001388529 0.001294036
0.000417251 0.001532515 0.003219957 0.005386112 0.007686454 0.006866554 0.011441497 0.016125266 0.014867934 0.013546933 0.012297511 0.011299637 0.010654504 0.010429678 0.010722744 0.011543073 0.012275316 0.012294957 0.011833064 0.011208636 0.010508332 0.009843444 0.009325344 0.008878591 0.007244867 0.005144411 0.004050702 0.003405225 0.00314464 0.002900768 0.002740328 0.002527287 0.002434092 0.002292839 0.002200731 0.002087451 0.001911761 0.001729974 0.001622177 0.001495531
0.000481567 0.001764052 0.003687828 0.006044738 0.008328866 0.00736245 0.011704316 0.016152946 0.01491115 0.013494749 0.012389759 0.011358427 0.010712578 0.010610687 0.011080299 0.011978293 0.012719998 0.012733005 0.012296932 0.011716076 0.011002061 0.010357951 0.009861826 0.00940499 0.007968178 0.00569998 0.004467629 0.003755781 0.003481343 0.003247401 0.003042919 0.002795217 0.002656596 0.002566414 0.002418649 0.002300119 0.002106033 0.001914664 0.00176175 0.001662
0.000515033 0.001946946 0.004000575 0.006454598 0.008781884 0.007703983 0.01181356 0.016185732 0.014842194 0.013501509 0.012402861 0.011449186 0.010837836 0.010639444 0.011198001 0.012321732 0.013045513 0.013081578 0.012692038 0.012003148 0.011333067 0.010722963 0.010186678 0.009786563 0.008512666 0.006106903 0.004819519 0.003971645 0.003708425 0.00344864 0.003218548 0.002984255 0.002846008 0.002698007 0.002578967 0.002419846 0.002225666 0.002051227 0.001889496 0.001771745
0.000529822 0.002032328 0.004176837 0.006659541 0.009038277 0.007874197 0.011906499 0.016076086 0.014895885 0.013520828 0.01236696 0.011390699 0.010881042 0.010732393 0.011331065 0.012431898 0.013235856 0.013190041 0.01282853 0.012165906 0.01144039 0.010828554 0.010354892 0.009956552 0.008728995 0.006182469 0.004968423 0.004113078 0.003821239 0.003558208 0.003358914 0.003090758 0.003034927 0.002795964 0.002660568 0.002537563 0.00231887 0.002128007 0.001968954 0.001811272
The vector below is the experimental adsorption isotherm on BPL activated carbon in units of, mol/g
It is designated "B" in the above paper
0.000007709
0.000018706
0.000040771
0.000083357
0.000146094
0.000235153
0.000362333
0.000596
0.000945
0.001386
0.001984
0.0026013
0.003139365
0.00351302
0.00380888
0.004039
0.00419049
0.004284
The vector below is the pressures at which experimental data were taken and GCMC simulation isotherms were calculated
# "p, Torr"
4.8
11.8
25.4
54.9
101.9
175.8
297.5
562.5
1085
1997.5
3620
6110
9272.5
12362.5
15552.5
18662.5
21165
22690